Phosphine-Substituted Diborane(4)yl Complexes of Tungsten
نویسندگان
چکیده
The reaction of the 1,2-dihalodiborane(4) B2(NMe2)2Cl2 with the lithium tungsten salts Li[(η5C5H5)(R3P)(OC)2W] [R = Me (3a), Ph (3b)] yields via alkali salt elimination the phosphinesubstituted diborane(4)yl tungsten complexes [(η-C5H5)(R3P)(OC)2W-{B(NMe2)-B(NMe2)Cl}] [R = Me (4a), Ph (4b)]. Both compounds have been fully characterized in solution by NMR and IR spectroscopy and 4a additionally by X-ray diffraction analysis.
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